Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(iv)O species

Literature Information

Publication Date 2004-10-14
DOI 10.1039/B412016G
Impact Factor 6.222
Authors

Tieme A. van den Berg, Johannes W. de Boer, Wesley R. Browne, Gerard Roelfes, Ben L. Feringa


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Abstract

Catalytic alkane oxidation with high selectivity using peracids and an (N4Py)Fe complex is presented and the role of [(N4Py)Fe(IV)O]2+ species, molecular oxygen and hydroxyl radicals in the catalysis is discussed.

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