Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(iv)O species
Literature Information
Tieme A. van den Berg, Johannes W. de Boer, Wesley R. Browne, Gerard Roelfes, Ben L. Feringa
Catalytic alkane oxidation with high selectivity using peracids and an (N4Py)Fe complex is presented and the role of [(N4Py)Fe(IV)O]2+ species, molecular oxygen and hydroxyl radicals in the catalysis is discussed.
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![(1S,2R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol structure (1S,2R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol structure](https://static.chemtradehub.com/structs/464/464-45-9-f88b.webp)