Bidentate amidineligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons

Literature Information

Publication Date 2004-09-29
DOI 10.1039/B411802B
Impact Factor 6.222
Authors

Masao Aoki, Motomu Kaneko, Sawa Izumi, Kazutoshi Ukai, Nobuharu Iwasawa


View Original

Abstract

Novel bidentate amidines were designed and synthesized as easily available electron-donating N-ligands for Ni0-mediated coupling of carbon dioxide with alkynes or allenes, and high regioselectivity was achieved even for the carboxylation of aryl substituted internal alkynes.

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