Bidentate amidineligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons
Literature Information
Masao Aoki, Motomu Kaneko, Sawa Izumi, Kazutoshi Ukai, Nobuharu Iwasawa
Novel bidentate amidines were designed and synthesized as easily available electron-donating N-ligands for Ni0-mediated coupling of carbon dioxide with alkynes or allenes, and high regioselectivity was achieved even for the carboxylation of aryl substituted internal alkynes.
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