Reversible and irreversible conformational changes in poly(isocyanide)s: a remote stereoelectronic effect

Literature Information

Publication Date 2004-12-08
DOI 10.1039/B411449C
Impact Factor 6.222
Authors

David B. Amabilino, José-Luis Serrano, Jaume Veciana


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Abstract

Poly(isocyanide)s prepared by diastereoselective polymerisation of two chiral monomers, which differ only in the presence of a nitro-group adjacent to the stereogenic group, exhibit long range chiral induction, but a surprising influence of a remote substituent on the conformation and stability of the secondary structure in the macromolecules.

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