[H3N(CH2)7NH3]8(CH3NH3)2Sn(iv)Sn(ii)12I46 – a mixed-valent hybrid compound with a uniquely templated defect-perovskite structure‡

Literature Information

Publication Date 2004-11-19
DOI 10.1039/B411322E
Impact Factor 6.222
Authors

Jun Guan, Zhongjia Tang, Arnold M. Guloy


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Abstract

The incorporation of H3N(CH2)7NH3 with CH3NH3SnI3 resulted in the formation of a mixed-valent and semiconducting (Eg = 0.84 eV) organic-based perovskite, [H3N(CH2)7NH3]8(CH3NH3)2Sn(IV)Sn(II)12I46, with a unique 3D defect-perovskite structure with ordered vacancies at the Sn and I sites.

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