Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: structural characterization of Claisen condensation adduct
Literature Information
Gabriela A. Grasa, Rohit Singh, Natalie M. Scott, Edwin D. Stevens, Steven P. Nolan
The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C–H bond activation. The structure of the product has been established by a single crystal diffraction study.
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