Anion dependence of Ag(i) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2
Literature Information
Brandi L. Schottel, John Bacsa, Kim R. Dunbar
The new compound [Ag2(bptz)3][AsF6]2, prepared from the reaction of bptz with Ag[AsF6] in CH3CN, is stable in solution as well as the solid-state and exhibits an unprecedented propeller arrangement of three bptz ligands spanning two Ag(I) ions with [AsF6]− anions located in the folds of the cation.
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