Stereoconservative Negishi arylation and alkynylation as an efficient approach to enantiopure 2,2′-diarylated 1,1′-binaphthyls
Literature Information
Publication Date
2004-10-01
DOI
10.1039/B410185E
Impact Factor
6.222
Authors
Katarína Krascsenicsová, Peter Walla, Peter Kasák, Georg Uray, C. Oliver Kappe, Martin Putala
View Original
Abstract
Negishi arylation and alkynylation of easily synthesized chiral 2,2′-diodo-1,1′-binaphthyl rapidly proceeds in refluxing THF utilizing controlled microwave irradiation, affording enantiopure 2,2′-diarylated 1,1′-binaphthyls in good to excellent yields.
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Chemical Communications
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