A simple, general and efficient ketone synthesis viaalkylation and dephosphinoylation of β-keto-diphenylphosphine oxides
Literature Information
Publication Date
2004-09-30
DOI
10.1039/B410144H
Impact Factor
6.222
Authors
David J. Fox, Daniel Sejer Pedersen, Stuart Warren
View Original
Abstract
Products of difficult ketone alkylation reactions can be made selectively via activation with a diphenylphosphinoyl group; subsequent dephosphinoylation is easily achieved in base.
Related Literature
Selective determination of thiols: a novel electroanalytical approach
Nathan S. Lawrence, James Davis, Li Jiang, Tim G. J. Jones, Steve N. Davis, Richard G. Compton
2000-03-20
Communication
DOI: 10.1039/B000985G
Energy efficiency and economic assessment of imported energy carriers based on renewable electricity
André Sternberg, Marius Holst, Tom Smolinka, Achim Schaadt, Christopher Hebling, Hans-Martin Henning
2020-02-05
Paper
DOI: 10.1039/D0SE00067A
Engineering the structural formula of N-doped molybdenum carbide nanowires for the deoxygenation of palmitic acid
Xiaozhen Chen, Xiao Chen, Chuang Li, Changhai Liang
2020-02-25
Paper
DOI: 10.1039/C9SE01307E
Cu2CoGeS4 nanocrystals for high performance aqueous polysulfide/iodide redox flow batteries: enhanced selectively towards the electrocatalytic conversion of polysulfides
Kai He, Tsegaye Tadesse Tsega, Nazakat Ali, Jiantao Zai, Shoushuang Huang, Xuefeng Qian, Zhiwen Chen
2020-03-18
Paper
DOI: 10.1039/C9SE01201J
Native fluorescence spectroscopic characterization of DMBA induced carcinogenesis in mice skin for the early detection of tissue transformation
Jeyasingh Ebenezar, Prakasa Rao Aruna, Singaravelu Ganesan
2015-04-13
Paper
DOI: 10.1039/C4AN00650J
Red phosphorus confined in hierarchical hollow surface-modified Co9S8 for enhanced sodium storage
Huani Li, Yuhao Zhang, Beihong Liu, Zhihui Gao, Genfu Zhao, Tingting Liu, Xiang Gao, Shubiao Xia, Hong Guo
2020-03-10
Paper
DOI: 10.1039/D0SE00251H
Fuel cell evaluation of anion exchange membranes based on poly(phenylene oxide) with different cationic group placement
Annika Carlson, Björn Eriksson, Joel S. Olsson, Göran Lindbergh, Carina Lagergren, Patric Jannasch, Rakel Wreland Lindström
2020-02-24
Paper
DOI: 10.1039/C9SE01143A
Methanol production from CO2via an integrated, formamide-assisted approach
Aswin Gopakumar, Tim Pfister, Gunay Imanzade, Gabriela Gastelu, Paul J. Dyson
2020-01-07
Paper
DOI: 10.1039/C9SE01141B
Correction: Hydrothermal synthesis of γ-MnOOH nanowires using sapless leaves as the reductant: an effective catalyst for the regio-specific epoxidation of β-ionone
Yuqing Luo, Xiaotian Guo, Wenjie Lu, Lei Yu, Huan Pang
2020-05-22
Correction
DOI: 10.1039/D0SE90039G
You might also like
Compound Q&A
What industries use 4-(4-tert-Butylphenyl)-1H-pyrazol-3-amine (CAS: 1015845-73-4)?
4-(4-tert-Butylphenyl)-1H-pyrazol-3-amine finds applications in various industri...
1015845-73-44-(4-tert-Butylpheny...
Compound Q&A
What industries use H3TATAB (CAS: 63557-10-8)?
H3TATAB is used in the pharmaceutical industry for the synthesis of certain orga...
63557-10-8H3TATAB
Compound Q&A
What are the main uses of 1-Ethyl-3-fluorobenzene (CAS: 696-39-9)?
1-Ethyl-3-fluorobenzene (CAS: 696-39-9) is primarily used as a precursor in the ...
696-39-91-Ethyl-3-fluorobenz...
Compound Q&A
What are the main uses of 1-(tert-Butoxycarbonyl)-4-(4-methoxyphenyl)pyrrolidine-3-carboxylic acid (CAS: 851484-94-1)?
1-(tert-Butoxycarbonyl)-4-(4-methoxyphenyl)pyrrolidine-3-carboxylic acid is prim...
851484-94-11-(tert-Butoxycarbon...
Compound Q&A
What are the physical and chemical properties of 1-Cyclobutyl-4-piperidinone (CAS: 359880-05-0)?
1-Cyclobutyl-4-piperidinone (CAS: 359880-05-0) is a colorless or white crystalli...
359880-05-01-Cyclobutyl-4-piper...
Compound Q&A
What is Pyridine-2,6-dicarboxylic acid mono-tert-butyl ester (CAS: 575433-76-0)?
Pyridine-2,6-dicarboxylic acid mono-tert-butyl ester (CAS: 575433-76-0) is a che...
575433-76-0Pyridine-2,6-dicarbo...
Compound Q&A
What is the market or research trend for 2,3-Difluorophenylalanine (CAS: 236754-62-4)?
The market for 2,3-Difluorophenylalanine (CAS: 236754-62-4) is growing with incr...
236754-62-42,3-Difluorophenylal...
Compound Q&A
How is (2-Hydroxy-1-naphthyl)boronic acid (CAS: 898257-48-2) typically synthesized?
(2-Hydroxy-1-naphthyl)boronic acid can be synthesized through the reduction of 2...
898257-48-2(2-Hydroxy-1-naphthy...
Compound Q&A
What are the physical and chemical properties of tert-Butyl (5-bromo-6-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl)carbamate (CAS: 1315351-28-0)?
This compound is a crystalline solid with a molecular weight of approximately 52...
1315351-28-0tert-Butyl (5-bromo-...
Compound Q&A
Are there alternatives to 5,7-Dihydroxy-4-oxo-2-(3,4,5-trihydroxyphenyl)-4H-chromen-3-yl beta-D-glucopyranoside (CAS: 19833-12-6) in synthesis?
While 5,7-Dihydroxy-4-oxo-2-(3,4,5-trihydroxyphenyl)-4H-chromen-3-yl beta-D-gluc...
19833-12-65,7-Dihydroxy-4-oxo-...
Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![Disodium (6R,7R)-7-{[(2R)-2-hydroxy-2-phenylacetyl]amino}-8-oxo-3-({[1-(sulfonatomethyl)-1H-tetrazol-5-yl]sulfanyl}methyl)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate structure](https://static.chemtradehub.com/structs/612/61270-78-8-6b58.webp "Disodium (6R,7R)-7-{[(2R)-2-hydroxy-2-phenylacetyl]amino}-8-oxo-3-({[1-(sulfonatomethyl)-1H-tetrazol-5-yl]sulfanyl}methyl)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate structure")
Disodium (6R,7R)-7-{[(2R)-2-hydroxy-2-phenylacetyl]amino}-8-oxo-3-({[1-(sulfonatomethyl)-1H-tetrazol-5-yl]sulfanyl}methyl)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate
CAS Number:
61270-78-8
Molecular Formula:
C18H16N6Na2O8S3
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.