New Pb–Pb bonds: syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate

Literature Information

Publication Date 2004-08-20
DOI 10.1039/B408860N
Impact Factor 6.222
Authors

Yuzhong Wang, Brandon Quillian, Pingrong Wei, Xiao-Juan Yang, Gregory H. Robinson


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Abstract

Reaction of lead(II) chloride with biphenylmagnesium bromide yields Bp3Pb–PbBp3 and [(THF)3Mg(μ-Cl)3Mg(THF)3][Pb(PbBp3)3] (Bp = biphenyl), which, upon single crystal X-ray crystallographic analysis, reveals an interesting variation of Pb–Pb bond distances.

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