Synchronous, time resolved, diffuse reflectance FT-IR, energy dispersive EXAFS (EDE) and mass spectrometric investigation of the behaviour of Rh catalysts during NO reduction by CO

Literature Information

Publication Date 2004-09-22
DOI 10.1039/B405694A
Impact Factor 6.222
Authors

Mark A. Newton, Bhrat Jyoti, Andrew J. Dent, Steven G. Fiddy


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Abstract

Synchronous, time resolved, infra-red, XAFS, and mass spectroscopies are simultaneously applied in situ to the investigation of the dynamic behaviour of Rh/Al2O3 catalysts during NO reduction by CO; NO conversion, and its kinetic character are closely correlated to the conversion of Rh(I) (predominantly RhI(CO)2) to Rh(0).

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