Novel aggregation of [Ni(thiolato)2(amine)2]-type square planes assisted by silver(i) ions

Literature Information

Publication Date 2004-09-01
DOI 10.1039/B404512B
Impact Factor 6.222
Authors

Takumi Konno, Masafumi Usami, Masakazu Hirotsu, Takashi Yoshimura, Tatsuya Kawamoto


View Original

Abstract

Treatment of [Ni(L)] [L = (−SCH2CH2NHC(CH3)–)2] with Ag+ in water gave a pinwheel-like S-bridged NiII3AgI2 structure in [Ag2{Ni(L)}3]2+, which further reacted with [Ni(L)] to produce a NiII4AgI2 structure in [Ag2{Ni(L)}4]2+ and a NiII7AgI4 structure in [Ag4{Ni(L)}7]4+.

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