First cation radical salt of a tetrathiafulvalene–based phosphine metal complex

Literature Information

Publication Date 2004-05-05
DOI 10.1039/B403168G
Impact Factor 6.222
Authors

Narcis Avarvari, Marc Fourmigué


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Abstract

Electrocrystallization of (o-P2)Mo(CO)4, where o-P2 is the tetrathiafulvalene-based chelating diphosphine o-Me2TTF-(PPh2)2, in the presence of the Linquist anion Mo6O192− affords a 2:1 salt, formulated as [(o-P2)Mo(CO)4]2[Mo6O19], with a Heisenberg spin chain magnetic behaviour.

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