First cation radical salt of a tetrathiafulvalene–based phosphine metal complex
Literature Information
Narcis Avarvari, Marc Fourmigué
Electrocrystallization of (o-P2)Mo(CO)4, where o-P2 is the tetrathiafulvalene-based chelating diphosphine o-Me2TTF-(PPh2)2, in the presence of the Linquist anion Mo6O192− affords a 2:1 salt, formulated as [(o-P2)Mo(CO)4]2[Mo6O19], with a Heisenberg spin chain magnetic behaviour.
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