Programmed single step self-assembly of a [2 × 2] grid architecture built on metallic centers of different coordination geometries
Literature Information
Publication Date
2004-04-23
DOI
10.1039/B402854F
Impact Factor
6.222
Authors
Anne Petitjean, Nathalie Kyritsakas, Jean-Marie Lehn
View Original
Abstract
A novel type of 2 × 2 grid type architecture incorporating two ions of different geometries results from the single step directed self-assembly of a bischelating ligand combining bridged bidentate and tridentate complexation subunits, designed so as to lead to the ion selective and toposelective introduction of two Zn(II) and two Cu(I) cations at well-defined, diagonally located positions of, respectively, octahedral and tetrahedral coordination geometry.
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Chemical Communications
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8.6
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Recommended Compounds
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[(2R)-6,6-Dimethyl-2-morpholinyl]methanol hydrochloride (1:1)
CAS Number:
1416444-88-6
Molecular Formula:
C7H16ClNO2
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(R)-N-[(S)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methylpropane-2-sulfinamide
CAS Number:
1595319-98-4
Molecular Formula:
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