Programmed single step self-assembly of a [2 × 2] grid architecture built on metallic centers of different coordination geometries
Literature Information
Anne Petitjean, Nathalie Kyritsakas, Jean-Marie Lehn
A novel type of 2 × 2 grid type architecture incorporating two ions of different geometries results from the single step directed self-assembly of a bischelating ligand combining bridged bidentate and tridentate complexation subunits, designed so as to lead to the ion selective and toposelective introduction of two Zn(II) and two Cu(I) cations at well-defined, diagonally located positions of, respectively, octahedral and tetrahedral coordination geometry.
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