Paramagnetic relaxation of cyclohexane radical cation in solution as measured by the method of time-resolved magnetic field effect
Literature Information
The method of time-resolved magnetic field effect was applied to measure the spin–lattice relaxation time T1 for radical cations of a number of cycloalkanes in n-hexane solution at room temperature. The T1 value for the Jahn–Teller active cyclohexane radical cation was found to be approximately 9 ns which was substantially shorter than typical values for organic radical ions. Based upon the similarity of effects that various factors had on the spin–lattice relaxation rate of the cyclohexane radical cation and the benzene radical anion it was proposed that the spin–orbital interaction made the predominant contribution to the relaxation of both radicals.
Recommended Journals
Related Literature
Band alignment and charge transfer predictions of ZnO/ZnX (X = S, Se or Te) interfaces applied to solar cells: a PBE+U theoretical study
Efracio Mamani Flores, Rogério Almeida Gouvea, Maurício Jeomar Piotrowski, Mário Lucio Moreira
DOI: 10.1039/C7CP08177D
Molecular dynamics investigations of cello-oligosaccharide recognition by Cel9G–CBM3c from Clostridium cellulovorans
Penghui Li, Chunchun Zhang
DOI: 10.1039/C7CP07175B
The influence of interactions between isotopoloques on coherent, ultrafast vibrational dynamics of liquid C2Cl4
B. Ratajska-Gadomska, W. Gadomski, J. Konarska, K. Polok
DOI: 10.1039/C7CP07928A
Spin–orbit coupling induced spin polarized valley states in SrRuO3/BiIrO3 heterostructures
Yanli Ji, Xiaocha Wang, Wenbo Mi
DOI: 10.1039/C8CP04336A
Solvation dynamics in polar solvents and imidazolium ionic liquids: failure of linear response approximations
Esther Heid, Christian Schröder
DOI: 10.1039/C7CP07052G
Detecting reactive islands using Lagrangian descriptors and the relevance to transition path sampling
Sarbani Patra, Srihari Keshavamurthy
DOI: 10.1039/C7CP05912D
A dynamical process of optically trapped singlet ground state 85Rb133Cs molecules produced via short-range photoassociation
DOI: 10.1039/C7CP07756D
Impact of screw and edge dislocations on the thermal conductivity of individual nanowires and bulk GaN: a molecular dynamics study
Anastasiia Salnikova, Imad Belabbas, David Lacroix, Joseph Kioseoglou
DOI: 10.1039/C7CP07821H
Structural transformations of carbon and boron nitride nanoscrolls at high impact collisions
C. F. Woellner, L. D. Machado, P. A. S. Autreto, D. S. Galvao
DOI: 10.1039/C7CP07402F
You might also like
What are the main uses of 1-(3-Aminophenyl)-3-[(3R)-1-(3,3-dimethyl-2-oxobutyl)-2-oxo-5-(2-pyridinyl)-2,3-dihydro-1H-1,4-benzodiazepin-3-yl]urea (CAS: 155412-88-7)?
This compound is mainly used as an intermediate in the synthesis of antipsychoti...
How should waste containing 1-(D-Ribofuranosyl)-1,4-dihydro-3-pyridinecarboxamide (CAS: 19132-12-8) be handled?
Waste containing 1-(D-Ribofuranosyl)-1,4-dihydro-3-pyridinecarboxamide (CAS: 191...
What regulatory guidelines apply to 2-Methyl-2-propanyl 3-bromo-3-(hydroxymethyl)-1-azetidinecarboxylate (CAS: 2007919-81-3)?
2-Methyl-2-propanyl 3-bromo-3-(hydroxymethyl)-1-azetidinecarboxylate (CAS: 20079...
What is N-(4-Chloro-2-pyridinyl)acetamide (CAS: 245056-66-0)?
N-(4-Chloro-2-pyridinyl)acetamide (CAS: 245056-66-0) is a chemical compound with...
What is 5-Chloro-2-hydroxybenzoic acid (CAS: 321-14-2)?
5-Chloro-2-hydroxybenzoic acid, also known as 5-chlorosalicylic acid, is an arom...
What precautions should be taken when handling 1,1-Dichloro-1-fluoroethane (CAS: 1717-00-6)?
When handling 1,1-Dichloro-1-fluoroethane (CAS: 1717-00-6), it is important to u...
What are the physical and chemical properties of Fmoc-(2S,3R)-3-phenylpyrrolidine-2-carboxylic acid (CAS: 281655-32-1)?
Fmoc-(2S,3R)-3-phenylpyrrolidine-2-carboxylic acid is a white crystalline solid ...
What are the main uses of 4-Amino-5-bromo-2-pyridinecarboxylic acid (CAS: 1363381-01-4)?
4-Amino-5-bromo-2-pyridinecarboxylic acid is primarily used as a precursor in th...
What precautions should be taken when handling (S)-tert-butyl 2-((2-(4-bromophenyl)-2-oxoethyl)carbamoyl)pyrrolidine-1-carboxylate (CAS: 1007881-98-2)?
Handling this compound should be done with personal protective equipment (PPE) i...
What precautions should be taken when handling 8-bromo-2,2-dimethyl-3,4-dihydro-2H-1,4-benzoxazin-3-one (CAS: 688363-73-7)?
When handling 8-bromo-2,2-dimethyl-3,4-dihydro-2H-1,4-benzoxazin-3-one, use prop...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine structure 4-Chloro-3-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridine structure](https://static.chemtradehub.com/structs/869/869335-75-1-a9d0.webp)

![6-Benzyl-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-c]pyridin-3(2H)-one structure 6-Benzyl-4,5,6,7-tetrahydro-1H-pyrazolo[3,4-c]pyridin-3(2H)-one structure](https://static.chemtradehub.com/structs/909/909187-64-0-f54f.webp)

