Mild and efficient palladium(ii)-catalyzed racemization of allenes
Literature Information
Attila Horváth, Jan-E. Bäckvall
Allenes undergo racemization in the presence of catalytic amounts of Pd(OAc)2/LiBr under mild conditions; the reaction proceeds via a bromopalladation–debromopalladation sequence and tolerates various functional groups.
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