Mild and efficient palladium(ii)-catalyzed racemization of allenes

Literature Information

Publication Date 2004-03-09
DOI 10.1039/B316482A
Impact Factor 6.222
Authors

Attila Horváth, Jan-E. Bäckvall


View Original

Abstract

Allenes undergo racemization in the presence of catalytic amounts of Pd(OAc)2/LiBr under mild conditions; the reaction proceeds via a bromopalladation–debromopalladation sequence and tolerates various functional groups.

Related Literature

Structural properties of the evolution of CTAB/NaSal micelles investigated by SANS and rheometry

Christopher N. Lam, Changwoo Do, Yangyang Wang, Guan-Rong Huang, Wei-Ren Chen

2019-08-07 Paper

DOI: 10.1039/C9CP02868D

Implicit solvent effects in the determination of Brønsted–Evans–Polanyi relationships for heterogeneously catalyzed reactions

José R. B. Gomes, Francesc Viñes, Francesc Illas, José L. C. Fajín

2019-07-17 Paper

DOI: 10.1039/C9CP02817J

Inside back cover

Cover

DOI: 10.1039/C9CP90212K

First-principles prediction of large thermoelectric efficiency in superionic Li2SnX3 (X = S, Se)

Enamul Haque, Claudio Cazorla, M. Anwar Hossain

2019-11-22 Paper

DOI: 10.1039/C9CP05939C

Directional and regioselective hole injection of spiropyran photoswitches intercalated into A/T-duplex DNA

Davide Avagliano, Pedro A. Sánchez-Murcia, Leticia González

2019-07-25 Paper

DOI: 10.1039/C9CP03398J

Disorder–order structural transition of single crystal hydrogen chloride under high pressure–temperature

Mengya Lu, Di Zhou, Fangfei Li, Yongfu Liang, Qiang Zhou, Xiaoli Huang, Tian Cui

2019-07-23 Paper

DOI: 10.1039/C9CP02839K

Polypyrrole derivatives for optoelectronic applications: a DFT study on the influence of side groups

Alex Pifer Coleone, Leonardo Gois Lascane

2019-07-23 Paper

DOI: 10.1039/C9CP02638J

The ionic liquid [C4mpy][Tf2N] induces bound-like structure in the intrinsically disordered protein FlgM

Erin E. Carter, Alexanndra J. Heyert, Mattheus De Souza, Joseph L. Baker

2019-07-31 Paper

DOI: 10.1039/C9CP01882D

Structural and reorientational dynamics of tetrahydroborate (BH4−) and tetrahydrofuran (THF) in a Mg(BH4)2·3THF adduct: neutron-scattering characterization

Marina Chong, Mark E. Bowden, Hui Wu, Wei Zhou, Iffat Nayyar, Bojana Ginovska, Thomas Gennett, Tom Autrey, Craig M. Jensen, Terrence J. Udovic

2019-11-20 Paper

DOI: 10.1039/C9CP03311D

You might also like

Compound Q&A

What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?

When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...

40716-16-34-Methyl-6-(trifluor...
Compound Q&A

What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?

4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...

405058-00-64-(3,5-Difluoropheny...
Compound Q&A

How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?

5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...

338982-07-35-{[4-(Trifluorometh...
Compound Q&A

What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?

The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...

6317-57-34-Benzylaniline hydr...
Compound Q&A

Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?

[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...

871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A

What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?

3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...

115929-62-93-Bromo-2,5-dimethox...
Compound Q&A

What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?

N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...

915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A

What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?

This compound is primarily used in the pharmaceutical industry for the synthesis...

24828-96-4Carbamic acid, N-[(5...
Compound Q&A

How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?

2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...

1298101-47-92-Methyl-2-propanyl ...
Compound Q&A

What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?

Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...

367-33-9Ethyl 2-bromo-4,4,4-...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.