Disorder–order structural transition of single crystal hydrogen chloride under high pressure–temperature

Literature Information

Publication Date 2019-07-23
DOI 10.1039/C9CP02839K
Impact Factor 3.676
Authors

Mengya Lu, Di Zhou, Fangfei Li, Yongfu Liang, Qiang Zhou, Xiaoli Huang, Tian Cui


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Abstract

Hydrogen chloride (HCl) is the simplest hydrogen-bonded molecule and has attracted a great deal of attention owing to its interesting structural changes triggered by pressure or temperature. The structural properties of solid HCl have been investigated by Brillouin scattering in the pressure range of 0–20 GPa under high temperature, combined with external heating in a diamond anvil cell. Three elastic constants and two moduli of the single crystal sample were observed at high pressure–temperature and each of them grows monotonously with pressure along a separate isotherm. The pressure dependence of elastic anisotropy proves that the disorder–order transition pressures are 4.5 GPa, 5.4 GPa and 8.8 GPa for the 300 K, 390 K and 470 K isotherms, respectively. The current work discovered the disorder–order structural transition in HCl and extended its phase diagram to the high pressure–temperature range, also providing a new insight into other simple hydrogen-bonded molecular compounds.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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