On the classification and representation of ternary phase diagrams: The yin and yang of a T–x approach
Literature Information
This article discusses some of the issues related to the classification and representation of ternary diagrams and how these can be incorporated into the more general framework of global phase diagrams. It is shown that the representation of binary mixtures in the form of T–x diagrams constitutes an insightful and logical approach to the problem of a systematic classification of fluid phase behaviour in terms of bifurcations (the yin and yang) and that the concept can be extended to the classification of ternary systems.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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