Static permittivity of water revisited: ε in the electric field above 108 V m−1 and in the temperature range 273 ≤ T ≤ 373 K

Literature Information

Publication Date 2004-02-19
DOI 10.1039/B314337F
Impact Factor 3.676
Authors

I. Danielewicz-Ferchmin, A. R. Ferchmin


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Abstract

Calculations are presented of the permittivity of water residing in conditions encountered in hydration shells. The present approach is applicable to water in high electric fields and in the whole range of temperature where it is liquid. Possible applications to various systems are mentioned. Static permittivity of aqueous solutions of exemplary salts is calculated and its comparison with experiment discussed in some detail.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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