Stereoselective ring-opening polymerization of racemic lactide using alkoxy-amino-bis(phenolate) group 3 metal complexes
Literature Information
Chen-Xin Cai, Abderramane Amgoune, Christian W. Lehmann, Jean-François Carpentier
Polymerization of racemic lactide initated by alkyl- and amido-yttrium complexes of a non-chiral tetradentate alkoxy-amino-bis(phenolate) ligand proceeds rapidly, in a controlled manner, to give heterotactic-rich polylactic acid.
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