Contrasting coordination behaviour of 22-membered chalcogenaaza (Se, Te) macrocylces towards Pd(ii) and Pt(ii): Isolation and structural characterization of the first metallamacrocyle with a C–Pt–Se linkage
Literature Information
Publication Date
2004-01-08
DOI
10.1039/B312358H
Impact Factor
6.222
Authors
Snigdha Panda, Harkesh B. Singh, Ray J. Butcher
View Original
Abstract
Interaction of the 22-membered selenaaza macrocyle 3 with Pt(II) leads to the formation of the novel cationic Pt(IV) metallamacrocylic complex 5via the oxidative addition of a C–Se bond to Pt(II), whereas corresponding reactions of 3 and 4 with Pd(II) afford cationic complexes 6 and 7 with differing ligating properties.
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Source Journal
Chemical Communications
CiteScore:
8.6
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4.7%
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2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
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CAS Number:
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Molecular Formula:
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