Synthesis and Bergman cyclization of a β-extended porphyrenediyne
Literature Information
John D. Spence, Eric D. Cline, Domingo M. LLagostera, Patrick S. O'Toole
Condensation of a porphyrin-2,3-dione with a 1,2-diaminoarenediyne affords a β-extended porphyrinic-enediyne: upon thermal Bergman cyclization the quinoxaline spacer positioned between the macrocycle and the enediyne prevents tandem radical cyclization to a picenoporphyrin.
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