Polyhedral monocarbaborane chemistry. Carboxylic acid derivatives of the [closo-2-CB9H10]− anion

Literature Information

Publication Date 2004-01-08
DOI 10.1039/B311853N
Impact Factor 6.222
Authors

Andreas Franken, Colin A. Kilner, John D. Kennedy


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Abstract

Reaction of B10H14 with para-(OHC)C6H4(COOH) in aqueous KOH gives the [nido-6-CB9H11-6-(C6H4-para-COOH)]− anion 1 which upon cluster closure with iodine in alkali solution gives the [closo-2-CB9H9-2-(C6H4-para-COOH)]− anion 2; an analogous procedure with B10H14 and glyoxalic acid OHCCOOH gives the [closo-2-CB9H9-2-(COOH)]− anion 4via the [arachno-6-CB9H13-6-(COOH)]− anion 3.

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