A new synthesis of 1,3-dihydrobenzo[1,2]oxasiloles by a novel rearrangement of a pentavalent silicon intermediate

Literature Information

Publication Date 2003-11-26
DOI 10.1039/B311804E
Impact Factor 6.222
Authors

George Bashiardes, Vanessa Chaussebourg, Géraldine Laverdan, Jacques Pornet


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Abstract

A new synthesis of benzo[1,2]oxasiloles is described, wherein an unprecedented intramolecular allylic transposition takes place probably involving a pentavalent silicon intermediate.

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Chemical Communications

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