Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2
Literature Information
Publication Date
2003-12-04
DOI
10.1039/B308741G
Impact Factor
6.222
Authors
Yasushi Nishihara, Hiroyuki Onodera, Kohtaro Osakada
View Original
Abstract
The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(II) complexes, trans-Pd(C6F5)I(PR3)2 (PR3 = PEt3, PMe2Ph, PMePh2) in the presence of Ag2O afforded trans-Pd(C6F5)(2,4,6-C6F3H2)(PR3)2 which are stabilized by fluorine atoms in the ortho positions.
Related Literature
Engineering the structural formula of N-doped molybdenum carbide nanowires for the deoxygenation of palmitic acid
Xiaozhen Chen, Xiao Chen, Chuang Li, Changhai Liang
2020-02-25
Paper
DOI: 10.1039/C9SE01307E
Cu2CoGeS4 nanocrystals for high performance aqueous polysulfide/iodide redox flow batteries: enhanced selectively towards the electrocatalytic conversion of polysulfides
Kai He, Tsegaye Tadesse Tsega, Nazakat Ali, Jiantao Zai, Shoushuang Huang, Xuefeng Qian, Zhiwen Chen
2020-03-18
Paper
DOI: 10.1039/C9SE01201J
Interplay between halides in the electrolyte and the chemical states of Cu in Cu-based electrodes determines the selectivity of the C2 product
Yang Yang, Kejian Li, Saira Ajmal, Yiqing Feng, Aziz-Ur-Rahim Bacha, Iqra Nabi
2020-02-17
Paper
DOI: 10.1039/C9SE01318K
Solvent selection and Pt decoration towards enhanced photocatalytic CO2 reduction over CsPbBr3 perovskite single crystals
Yi-Xin Chen, Yang-Fan Xu, Xu-Dong Wang, Hong-Yan Chen, Dai-Bin Kuang
2020-02-10
Paper
DOI: 10.1039/C9SE01218D
Are MXenes suitable as cathode materials for rechargeable Mg batteries?
Henning Kaland, Jacob Hadler-Jacobsen, Frode Håskjold Fagerli, Sverre M. Selbach, Kjell Wiik, Sondre Kvalvåg Schnell
2020-03-19
Paper
DOI: 10.1039/D0SE00087F
Correction: Highly penetrative liposome nanomedicine generated by a biomimetic strategy for enhanced cancer chemotherapy
Zonghai Sheng, Dehong Hu, Fei Yan, Guanhui Gao, Pan Wang, Xin Liu, Hairong Zheng
2021-05-13
Correction
DOI: 10.1039/D1BM90047A
Construction of a nanocavity structure with a carrier-selective layer for enhancement of photocatalytic hydrogen production performance
Qin Lei, Jihua Tan, Xinxin Long, Huanyu Chen, Zhongfang Lei, Zhenya Zhang
2019-12-14
Paper
DOI: 10.1039/C9SE00987F
A P-doped PtTe mesoporous nanotube electrocatalyst
Ziqiang Wang, Hugang Zhang, Shuli Yin, Songliang Liu, Zechuan Dai, You Xu, Xiaonian Li, Liang Wang, Hongjing Wang
2020-04-02
Paper
DOI: 10.1039/D0SE00326C
Structural reduced graphene oxide supercapacitors mechanically enhanced with tannic acid
Paraskevi Flouda, Junyeong Yun, Dimitrios Loufakis, Smit A. Shah, Micah J. Green, Jodie L. Lutkenhaus
2020-02-25
Paper
DOI: 10.1039/C9SE01299K
Solid-state transformation of aqueous to organic electrolyte – Enhancing the operating voltage window of ‘in situ electrolyte’ supercapacitors
Desirée Leistenschneider, Lars Henning Heß, Andrea Balducci, Lars Borchardt
2020-02-26
Paper
DOI: 10.1039/D0SE00180E
You might also like
Compound Q&A
What industries use 4-(4-tert-Butylphenyl)-1H-pyrazol-3-amine (CAS: 1015845-73-4)?
4-(4-tert-Butylphenyl)-1H-pyrazol-3-amine finds applications in various industri...
1015845-73-44-(4-tert-Butylpheny...
Compound Q&A
What industries use H3TATAB (CAS: 63557-10-8)?
H3TATAB is used in the pharmaceutical industry for the synthesis of certain orga...
63557-10-8H3TATAB
Compound Q&A
What are the main uses of 1-Ethyl-3-fluorobenzene (CAS: 696-39-9)?
1-Ethyl-3-fluorobenzene (CAS: 696-39-9) is primarily used as a precursor in the ...
696-39-91-Ethyl-3-fluorobenz...
Compound Q&A
What are the main uses of 1-(tert-Butoxycarbonyl)-4-(4-methoxyphenyl)pyrrolidine-3-carboxylic acid (CAS: 851484-94-1)?
1-(tert-Butoxycarbonyl)-4-(4-methoxyphenyl)pyrrolidine-3-carboxylic acid is prim...
851484-94-11-(tert-Butoxycarbon...
Compound Q&A
What are the physical and chemical properties of 1-Cyclobutyl-4-piperidinone (CAS: 359880-05-0)?
1-Cyclobutyl-4-piperidinone (CAS: 359880-05-0) is a colorless or white crystalli...
359880-05-01-Cyclobutyl-4-piper...
Compound Q&A
What is Pyridine-2,6-dicarboxylic acid mono-tert-butyl ester (CAS: 575433-76-0)?
Pyridine-2,6-dicarboxylic acid mono-tert-butyl ester (CAS: 575433-76-0) is a che...
575433-76-0Pyridine-2,6-dicarbo...
Compound Q&A
What is the market or research trend for 2,3-Difluorophenylalanine (CAS: 236754-62-4)?
The market for 2,3-Difluorophenylalanine (CAS: 236754-62-4) is growing with incr...
236754-62-42,3-Difluorophenylal...
Compound Q&A
How is (2-Hydroxy-1-naphthyl)boronic acid (CAS: 898257-48-2) typically synthesized?
(2-Hydroxy-1-naphthyl)boronic acid can be synthesized through the reduction of 2...
898257-48-2(2-Hydroxy-1-naphthy...
Compound Q&A
What are the physical and chemical properties of tert-Butyl (5-bromo-6-methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-yl)carbamate (CAS: 1315351-28-0)?
This compound is a crystalline solid with a molecular weight of approximately 52...
1315351-28-0tert-Butyl (5-bromo-...
Compound Q&A
Are there alternatives to 5,7-Dihydroxy-4-oxo-2-(3,4,5-trihydroxyphenyl)-4H-chromen-3-yl beta-D-glucopyranoside (CAS: 19833-12-6) in synthesis?
While 5,7-Dihydroxy-4-oxo-2-(3,4,5-trihydroxyphenyl)-4H-chromen-3-yl beta-D-gluc...
19833-12-65,7-Dihydroxy-4-oxo-...
Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.