The first structurally characterised perchlorato-cobalt(iii) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane
Literature Information
Xiangting Zhou, Anthony I. Day, Anthony C. Willis, W. Gregory Jackson
Two isomeric C-bonded complexes, sym-anti-[Co(L-C)(OH2)]2+ and sym-syn-[Co(L-C)(OH2)]2+ (L = 1,4,8,11-tetraazabicyclo[9.5.2]octadecane) when crystallised from aqueous NaClO4 remarkably yielded the corresponding perchlorato complexes, confirmed by the single crystal X-ray structures.
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