Stereospecific isomerisation of P-heterocycles triggered by coordination: synthesis of the first P,N-chelates featuring a 2-phospholene moiety

Literature Information

Publication Date 2003-06-16
DOI 10.1039/B304308H
Impact Factor 6.222
Authors

François Leca, Mathieu Sauthier, Boris le Guennic, Christophe Lescop, Loic Toupet, Jean-François Halet, Régis Réau


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Abstract

Coordination of 2-(2-pyridyl)phospholes on Pd(II) centres results in a ring strain sufficient to induce a stereospecific [1,3]-H migration affording the corresponding phospholene ligands.

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