Stereospecific isomerisation of P-heterocycles triggered by coordination: synthesis of the first P,N-chelates featuring a 2-phospholene moiety
Literature Information
François Leca, Mathieu Sauthier, Boris le Guennic, Christophe Lescop, Loic Toupet, Jean-François Halet, Régis Réau
Coordination of 2-(2-pyridyl)phospholes on Pd(II) centres results in a ring strain sufficient to induce a stereospecific [1,3]-H migration affording the corresponding phospholene ligands.
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