Renewable camphor-derived hydroperoxide: synthesis and use in the asymmetric epoxidation of allylic alcohols

Literature Information

Publication Date 2003-05-16
DOI 10.1039/B303904H
Impact Factor 6.222
Authors

Alessandra Lattanzi, Patrizia Iannece, Assunta Vicinanza, Arrigo Scettri


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Abstract

Renewable enantiopure tertiary furyl hydroperoxide has been easily synthesized in two steps starting from low cost (+)-(1R)-camphor and it has been used in the asymmetric epoxidation and kinetic resolution of allylic alcohols (enantioselectivities up to 46%).

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