Chiral shape and enantioselective growth of colloidal particles of self-assembled meso-tetra(phenyl and 4-sulfonatophenyl)porphyrins

Literature Information

Publication Date 2003-05-29
DOI 10.1039/B303273F
Impact Factor 6.222
Authors

Joaquim Crusats, Josep Claret, Ismael Díez-Pérez, Zoubir El-Hachemi, Héctor García-Ortega, Raimon Rubires, Francesc Sagués, Josep M. Ribó


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Abstract

The self-assembly of diprotonated phenyl and 4-sulfonatophenyl meso-tetrasubstituted porphyrins gives a spontaneous chiral symmetry breaking, but only for H2TPPS3−, which forms helicoidal colloidal particles; the selection of the resulting chirality sign by the hydrodynamic forces of a stirring vortex can be demonstrated.

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