Photomediated asymmetric synthesis of (−)-cuparene

Literature Information

Publication Date 2003-03-31
DOI 10.1039/B300815K
Impact Factor 6.222
Authors

Richard S. Grainger, Aslam Patel


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Abstract

Generation of a benzylic quaternary stereocentre via the photomediated cyclisation of a chiral α-(aminobutyl)styrene followed by a microwave-assisted Cope elimination has led to a total synthesis of the sesquiterpene (−)-cuparene.

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