Heterogeneous vibrational relaxation of carbon monoxide
Literature Information
Galina M. Grigorian, Adam Cenian
The first results relating to heterogeneous vibrational relaxation of carbon monoxide in an Al2O3 ceramics tube are reported, together with an estimation of its probability. It was found that the probability of heterogeneous relaxation εv of the first-excited state of CO on the Al2O3 surface lies in the range (5 to 7) × 10−2. The measurements show that the probabilities of heterogeneous relaxation of CO(X1Σ, v) do not depend on the value of v, at least for v = 1, 2 and 3.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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