Time resolved FTIR emission measurements of the internal energies of NO formed in the O(1D) + N2O reaction, and energy transfer processes to N2O

Literature Information

Publication Date 2003-04-23
DOI 10.1039/B300163F
Impact Factor 3.676
Authors

Gus Hancock, Vanessa Haverd


View Original

Abstract

Time resolved infrared emission from the fundamental and first overtone transitions of NO(v = 1–14), produced in the reaction of N2O with O(1D) has been analysed to determine the nascent vibrational distribution of NO. The electronically excited O atom was produced by the 193 nm laser photolysis of N2O. The measured vibrational distribution was found to be monotonically decreasing as a function of increasing v. Lower limits were determined for the average nascent rotational energy in v = 1–6, ranging from 4660 cm−1 (v = 1) to 3050 cm−1 (v = 6). Emission from N2O(011) was also observed and found to be attributable to energy transfer from internally excited N2 formed by photolysis of N2O. The relative yields of NO(v) and N2O(011) provided indirect evidence for a yield of at least 3.5% for N2(v = 1) produced by 193 nm photolysis of N2O.

Related Literature

Raman microspectroscopy and vibrational sum frequency generation spectroscopy as probes of the bulk and surface compositions of size-resolved sea spray aerosol particles

Andrew P. Ault, Defeng Zhao, Carlena J. Ebben, Michael J. Tauber, Franz M. Geiger, Vicki H. Grassian

2013-02-19 Paper

DOI: 10.1039/C3CP43899F

Co–Ni layered double hydroxides for water oxidation in neutral electrolyte

Ye Zhang, Bai Cui, Chunsong Zhao, Hong Lin

2013-03-18 Paper

DOI: 10.1039/C3CP50202C

The effect of axial ligand on the oxidation of syringyl alcohol by Co(salen) adducts

Thomas Elder, Joseph J. Bozell, Diana Cedeno

2013-04-03 Paper

DOI: 10.1039/C3CP44404J

Recovering degraded quasi-solid-state dye-sensitized solar cells by applying electrical pulses

Xi Zhang, Xuezhen Huang

2013-03-14 Paper

DOI: 10.1039/C3CP51071A

Inside front cover

Cover

DOI: 10.1039/C3CP90043F

Density-induced molecular arrangements of water inside carbon nanotubes

M. Sadeghi

2013-03-18 Paper

DOI: 10.1039/C3CP44563A

On the signature of the hydrophobic effect at a single molecule level

Giuseppe Graziano

2013-03-25 Paper

DOI: 10.1039/C3CP50616A

Analysis of visible-light-active Sn(ii)–TiO2 photocatalysts

Venkata Bharat Ram Boppana, Feng Jiao, Dave Newby, Jr., Jude Laverock, Kevin E. Smith, Jean Claude Jumas, Greg Hutchings, Raul F. Lobo

2013-03-13 Communication

DOI: 10.1039/C3CP44635B

You might also like

Compound Q&A

What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?

When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...

79206-94-34-(2-Furylmethyl)thi...
Compound Q&A

What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?

When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...

71320-77-94-Chloro-N-[2-(4-mor...
Compound Q&A

How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?

Waste containing this compound (CAS: 62921-74-8) should be handled according to ...

62921-74-82-[2-(2-Methoxyethox...
Compound Q&A

How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?

Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...

40056-18-6(S)-Methyl 2-amino-3...
166882-70-85-({4-[(2S,4R)-4-Hyd...
Compound Q&A

Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?

There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...

7312-27-8(2E)-3-(3,4-Dichloro...
Compound Q&A

How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?

Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...

925437-84-9Ethyl 6-(2-nitrophen...
Compound Q&A

How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?

Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...

18453-07-12-(1,3-Thiazol-2-yl)...
Compound Q&A

How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?

Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...

103440-54-6Methyl 5-iodo-2-meth...
Compound Q&A

How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?

5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...

1427399-34-55-Chloro[1,2,4]triaz...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.