Liquid clathrate formation in ionic liquid–aromatic mixtures

Literature Information

Publication Date 2003-01-21
DOI 10.1039/B212726A
Impact Factor 6.222
Authors

John D. Holbrey, W. Matthew Reichert, Mark Nieuwenhuyzen, Oonagh Sheppard, Robin D. Rogers


View Original

Abstract

1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate–benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2∶1 inclusion compound.

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