One- and three-dimensional infinite arrays of Cu(i) ions exhibited by [Cu(NH3)2]Br and [Cu(NH3)Cl] in the solid state
Literature Information
Günter Margraf, Jan W. Bats, Michael Bolte, Hans-Wolfram Lerner, Matthias Wagner
In the solid state, [Cu(NH3)Cl] forms a three-dimensional network with each CuI ion being surrounded by three other CuI centres in a trigonal-planar fashion [Cu⋯Cu = 2.979(1) Å; cubic space group I213], whereas in [Cu(NH3)2]Br the cations establish infinite linear (Cu⋯Cu)∞ chains spanning the crystal lattice [Cu⋯Cu = 2.931(1) Å; monoclinic space group C2/c].
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