The levelling effect of solvational imbalances in the reactions of oximate α-nucleophiles with electrophilic phosphorus centers. Relevance to detoxification of organophosphorus esters
Literature Information
F. Terrier, E. Le Guével, A. P. Chatrousse, G. Moutiers, E. Buncel
A study of the reactions of oximate α-nucleophiles with diisopropylphosphorofluoridate (DFP) and two model phosphonates, has revealed either a levelling-off in reactivity or a bell-shaped behaviour in accordance with a critical decoupling of desolvation and bond formation (solvational imbalances); the relevance of these results to detoxification is emphasized.
Related Literature
Structural, dynamic and photophysical properties of a fluorescent dye incorporated in an amorphous hydrophobic polymer bundle
N. De Mitri, G. Prampolini, V. Barone
DOI: 10.1039/C4CP01828A
Assessing the hydration free energy of a homologous series of polyols with classical and quantum mechanical solvation models
Thaciana Malaspina, Leonardo M. Abreu, Tertius L. Fonseca, Eudes Fileti
DOI: 10.1039/C4CP02493A
Electric field induced hydrogenation of silicene
Weichang Wu, Zhimin Ao, Tao Wang, Changming Li, Sean Li
DOI: 10.1039/C4CP01416B
Adsorbate induced vacancy formation on silver surfaces
Tulio C. R. Rocha, Axel Knop-Gericke, Catherine Stampfl, Robert Schlögl, Simone Piccinin
DOI: 10.1039/C4CP00778F
Fe–N bonding in a carbon nanotube–graphene complex for oxygen reduction: an XAS study
Paul N. Duchesne, Yongfeng Hu, Jian Wang, Peng Zhang, Yanguang Li, Tom Regier, Hongjie Dai
DOI: 10.1039/C4CP01455C
Energy transfer in aggregates of bacteriochlorophyll c self-assembled with azulene derivatives
Martina Matěnová, Florian-Xuan Dang, Petr Pospíšil, Jan Alster, Jaroslav V. Burda, Jakub Pšenčík
DOI: 10.1039/C4CP01311E
Vibronic structures and dynamics of the predissociating dimethyl sulfide and its isotopomers (CH3SCH3, CD3SCD3, CH3SCD3) at the conical intersection
Jun-Ho Yoon, Kyung Chul Woo, Sang Kyu Kim
DOI: 10.1039/C3CP55220A
Isothermal Onsager matrices and acceptor size effect on mass/charge transport properties of La1.9A0.1NiO3.95+δ (A = Ca, Sr)
Hong-Seok Kim, Han-Ill Yoo
DOI: 10.1039/C3CP55228D
Enhancing the hydrogen storage capacity of TiFe by utilizing clusters
Keisuke Takahashi, Shigehito Isobe
DOI: 10.1039/C4CP02204A
Fluorescence resonance energy transfer of gas-phase ions under ultra high vacuum and ambient conditions
Vladimir Frankevich, Vitaliy Chagovets, Fanny Widjaja, Konstantin Barylyuk, Zhiyi Yang, Renato Zenobi
DOI: 10.1039/C3CP54521K
You might also like
What are the main uses of (3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8)?
(3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8) is primari...
What regulatory guidelines apply to 5-(aminomethyl)-2-methoxyphenol (CAS: 89702-89-6)?
5-(Aminomethyl)-2-methoxyphenol (CAS: 89702-89-6) is classified under GHS as a s...
What is Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7)?
Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7) is a heterocyclic organic compo...
Is 1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride (CAS: 1185311-28-7) safe?
1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride is generally ...
What regulatory guidelines apply to [(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2)?
[(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2) is regulated und...
What regulatory guidelines apply to 6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7)?
6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7) falls under the scope of the Glob...
What industries use (2R)-1-(1-Benzofuran-2-yl)-N-propyl-2-pentanamine (CAS: 260550-89-8)?
This compound is primarily used in the pharmaceutical industry for the developme...
What are the main uses of 1-Ethyl-7-[2-methyl-6-(4H-1,2,4-triazol-3-yl)-3-pyridinyl]-3,5-dihydropyrazino[2,3-b]pyrazin-2(1H)-one (CAS: 1228013-15-7)?
1-Ethyl-7-[2-methyl-6-(4H-1,2,4-triazol-3-yl)-3-pyridinyl]-3,5-dihydropyrazino[2...
Are there alternatives to {5-(Acryloylamino)-2-[(dimethylamino)methyl]phenyl}boronic acid (CAS: 1217500-78-1) in synthesis?
Alternative reagents such as 2-[(dimethylamino)methyl]phenylboronic acid or rela...
What is 3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2)?
3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2) is an organic compound with the...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry











![4-[(4-Bromophenyl)sulfonyl]thiomorpholine structure 4-[(4-Bromophenyl)sulfonyl]thiomorpholine structure](https://static.chemtradehub.com/structs/223/223555-81-5-2d67.webp)


