Aqueous organometallic reactions of rhodium porphyrins: equilibrium thermodynamics

Literature Information

Publication Date 2003-01-17
DOI 10.1039/B212027E
Impact Factor 6.222
Authors

Xuefeng Fu, Leah Basickes, Bradford B. Wayland


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Abstract

The reactivity and equilibrium thermodynamic studies of tetra-p-sulfonatophenyl porphyrin rhodium hydride ([(TSPP)Rh–D]−4) with CO, aldehydes and olefins that produce formyl, α-hydroxyalkyl and alkyl complexes have been explored in water and compared with the related reactions in non-aqueous media.

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