First example of a tetra-carboxylate bridged dimanganese species

Literature Information

Publication Date 2003-01-23
DOI 10.1039/B211886F
Impact Factor 6.222
Authors

Abdessamad Grirrane, Antonio Pastor, Agustín Galindo, Andrea Ienco, Carlo Mealli, Patrick Rosa


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Abstract

The compound [Mn(tda)(bipy)] (tda = S(CH2COO)22−) features the first structurally characterized tetra-carboxylate dimanganese antiferromagnetic system with ‘copper acetate’ core; the binuclear units, completed by bipyridine chelates, are doubly chained by the tda anions that adopt an unprecedented μ,μ′-η1,η1,η1,η1 coordination mode.

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