Carbon–fluorine bond activation—looking at and learning from unsolvated systems

Literature Information

Publication Date 2003-04-04
DOI 10.1039/B211850E
Impact Factor 6.222
Authors

Ulf Mazurek, Helmut Schwarz


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Abstract

The selective activation of a particular bond in a molecule has always been a desideratum in chemical synthesis. This Feature Article focuses on studying the mechanisms operative in the activation of carbon–fluorine bonds beyond solvated systems, i.e., on surfaces and in the gas phase. Side glances to reactions in solutions, however, are incorporated when appropriate.

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