Potassium–zinc induced synergic enhancement of the basicity of hexamethyldisilazide (HMDS) towards methylbenzene molecules
Literature Information
William Clegg, Glenn C. Forbes, Alan R. Kennedy, Robert E. Mulvey, Stephen T. Liddle
While neither KHMDS nor Zn(HMDS)2 can unilaterally metallate toluene under the conditions studied, the bilateral base ‘KZn(HMDS)3’ can smoothly do so to produce the benzyl product [{KZn(HMDS)2(CH2Ph)}∞], which exists in the crystal as an infinite spiral chain of benzyl (ambi-σ, π)-linked (KNZnN) rings.
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