A novel reaction of dimethylsulfonium methylide with Michael acceptors: application to the synthesis of difficultly accessible vinylsilanes and styrenes

Literature Information

Publication Date 2003-02-07
DOI 10.1039/B211279E
Impact Factor 6.222
Authors

Sunil K. Ghosh, Rekha Singh, Sonali M. Date


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Abstract

Rather than the usual cyclopropanation and Peterson-type olefination, conditions for a novel elimination reaction from the adduct of dimethylsulfonium methylide and 2-silylalkylidene/arylidene malonate/cyanoacetate/phosphonoacetate leading to geminally substituted vinyl silanes or styrenes, respectively, have been established.

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