A novel reaction of dimethylsulfonium methylide with Michael acceptors: application to the synthesis of difficultly accessible vinylsilanes and styrenes
Literature Information
Sunil K. Ghosh, Rekha Singh, Sonali M. Date
Rather than the usual cyclopropanation and Peterson-type olefination, conditions for a novel elimination reaction from the adduct of dimethylsulfonium methylide and 2-silylalkylidene/arylidene malonate/cyanoacetate/phosphonoacetate leading to geminally substituted vinyl silanes or styrenes, respectively, have been established.
Recommended Journals
Related Literature
Fe–N bonding in a carbon nanotube–graphene complex for oxygen reduction: an XAS study
Paul N. Duchesne, Yongfeng Hu, Jian Wang, Peng Zhang, Yanguang Li, Tom Regier, Hongjie Dai
DOI: 10.1039/C4CP01455C
Fluorescence resonance energy transfer of gas-phase ions under ultra high vacuum and ambient conditions
Vladimir Frankevich, Vitaliy Chagovets, Fanny Widjaja, Konstantin Barylyuk, Zhiyi Yang, Renato Zenobi
DOI: 10.1039/C3CP54521K
Electric field induced hydrogenation of silicene
Weichang Wu, Zhimin Ao, Tao Wang, Changming Li, Sean Li
DOI: 10.1039/C4CP01416B
Edge state modulation of bilayer Bi nanoribbons by atom adsorption
Guangliang Cui, Pinhua Zhang
DOI: 10.1039/C4CP02213K
Photocatalytic reduction of o-chloronitrobenzene under visible light irradiation over CdS quantum dot sensitized TiO2
DOI: 10.1039/C4CP01250J
A quantum chemical study on gas phase decomposition pathways of triethylgallane (TEG, Ga(C2H5)3) and tert-butylphosphine (TBP, PH2(t-C4H9)) under MOVPE conditions
Andreas Stegmüller, Phil Rosenow, Ralf Tonner
DOI: 10.1039/C4CP01584C
A synergic effect of sodium on the phase transition of tungsten-doped vanadium dioxide
Qiang Song, Weitao Gong, Guiling Ning, Hassan Mehdi, Guiqi Zhang, Junwei Ye, Yuan Lin
DOI: 10.1039/C4CP00366G
Thermodynamic and kinetic analysis of heterogeneous photocatalysis for semiconductor systems
Baoshun Liu, Xiujian Zhao, Akira Fujishima
DOI: 10.1039/C3CP55317E
Unexpected strong magnetism of Cu doped single-layer MoS2 and its origin
J. D. Lee
DOI: 10.1039/C4CP00247D
You might also like
What are the main uses of (3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8)?
(3.beta.)-3-Hydroxy-N,N-dimethyl-chol-5-en-24-amide (CAS: 79066-03-8) is primari...
What regulatory guidelines apply to 5-(aminomethyl)-2-methoxyphenol (CAS: 89702-89-6)?
5-(Aminomethyl)-2-methoxyphenol (CAS: 89702-89-6) is classified under GHS as a s...
What is Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7)?
Thieno[2,3-c]pyridin-7(6H)-one (CAS: 28981-13-7) is a heterocyclic organic compo...
Is 1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride (CAS: 1185311-28-7) safe?
1-[(6-Methoxy-3-pyridinyl)methyl]-4-piperidinamine dihydrochloride is generally ...
What regulatory guidelines apply to [(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2)?
[(2E)-3-Phenyl-2-propen-1-yl]phosphonic acid (CAS: 146404-58-2) is regulated und...
What regulatory guidelines apply to 6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7)?
6-Bromo-7-methoxyquinoline (CAS: 1620515-86-7) falls under the scope of the Glob...
What industries use (2R)-1-(1-Benzofuran-2-yl)-N-propyl-2-pentanamine (CAS: 260550-89-8)?
This compound is primarily used in the pharmaceutical industry for the developme...
What are the main uses of 1-Ethyl-7-[2-methyl-6-(4H-1,2,4-triazol-3-yl)-3-pyridinyl]-3,5-dihydropyrazino[2,3-b]pyrazin-2(1H)-one (CAS: 1228013-15-7)?
1-Ethyl-7-[2-methyl-6-(4H-1,2,4-triazol-3-yl)-3-pyridinyl]-3,5-dihydropyrazino[2...
Are there alternatives to {5-(Acryloylamino)-2-[(dimethylamino)methyl]phenyl}boronic acid (CAS: 1217500-78-1) in synthesis?
Alternative reagents such as 2-[(dimethylamino)methyl]phenylboronic acid or rela...
What is 3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2)?
3-(Piperidin-4-yloxy)pyridine (CAS: 310881-48-2) is an organic compound with the...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry










![(3E)-3-[4-Hydroxy-3,5-bis(2-methyl-2-propanyl)benzylidene]dihydro-2(3H)-furanone structure (3E)-3-[4-Hydroxy-3,5-bis(2-methyl-2-propanyl)benzylidene]dihydro-2(3H)-furanone structure](https://static.chemtradehub.com/structs/102/102271-49-8-cba7.webp)

![N-[4-(Cyanoethynyl)phenyl]-16-oxo-4,7,10,13-tetraoxa-17-azahenicos-1-yn-21-amide structure N-[4-(Cyanoethynyl)phenyl]-16-oxo-4,7,10,13-tetraoxa-17-azahenicos-1-yn-21-amide structure](https://static.chemtradehub.com/structs/218/2183440-36-8-68cb.webp)

![Bis(N,N''-dimethylpiperazine)tetra[copper(I) iodide] structure Bis(N,N''-dimethylpiperazine)tetra[copper(I) iodide] structure](https://static.chemtradehub.com/structs/140/1401708-91-5-2b86.webp)