Mono(sulfido)-bridged mixed-valence nitrosyl complex: protonation and oxidative addition of iodine across the Ir(ii)–Ir(0) bond
Literature Information
Takanori Hattori, Shoji Matsukawa, Shigeki Kuwata, Youichi Ishii, Masanobu Hidai
Treatment of [Cp*IrH(SH)(PMe3)] (Cp* = η5-C5Me5) with [IrCl2(NO)(PPh3)2] in the presence of triethylamine yielded the sulfido-bridged IrIIIr0 complex [Cp*Ir(PMe3)(μ-S)Ir(NO)(PPh3)], which further reacted with I2 and triflic acid to give the diiodo complex [Cp*Ir(PMe3)(μ-I)(μ-S)IrI(NO)(PPh3)] and the hydrido complex [Cp*Ir(PMe3)(μ-H)(μ-S)Ir(NO)(PPh3)][OSO2CF3], respectively.
Related Literature
Dual nanocomposite multihollow polymer microspheres prepared by suspension polymerization based on a multiple pickering emulsion
Quanxing Gao, Chaoyang Wang, Hongxia Liu, Yunhua Chen, Zhen Tong
DOI: 10.1039/B9PY00255C
Steps, hops and turns: examining the effects of channel shapes on mass transfer in continuous electrochemical reactors
Hamish R. Stephen, Sarah Boyall, Christiane Schotten, Richard A. Bourne, Nikil Kapur, Charlotte E. Willans
DOI: 10.1039/D1RE00530H
One-pot three-step mechanically assisted synthesis and catalytic performance of tripodal metallic complexes
Raquel Viveiros, Teresa Casimiro
DOI: 10.1039/D1RE00194A
Sequence-controlled polymerizations: the next Holy Grail in polymer science?
Jean-François Lutz
DOI: 10.1039/B9PY00329K
Development of a high intensity parallel photoreactor for high throughput screening
Ning Qi, Michael K. Wismer, Donald V. Conway, Shane W. Krska, Spencer D. Dreher, Shishi Lin
DOI: 10.1039/D1RE00317H
α-Oxygenation of N-aryl/alkyl heterocyclic compounds via ruthenium photocatalysis
DOI: 10.1039/D1RE00200G
Carbonic anhydrase/formate dehydrogenase bienzymatic system for CO2 capture, utilization and storage
Ryohei Sato
DOI: 10.1039/D1RE00405K
Towards chiral polystyrene based materials: controlled polymerization of p-(2,2′-diphenylethyl)styrene
Christiane Hohberger, Klaus Beckerle, Jun Okuda
DOI: 10.1039/B9PY00286C
You might also like
What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?
When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...
Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?
4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...
How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?
Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...
What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?
5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...
How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?
Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...
What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?
4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...
How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?
Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...
What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?
6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...
Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?
(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...
What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?
7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry










![6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde structure 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde structure](https://static.chemtradehub.com/structs/564/564-94-3-e746.webp)
![5,10-Dihydroindeno[2,1-a]indene structure 5,10-Dihydroindeno[2,1-a]indene structure](https://static.chemtradehub.com/structs/654/6543-29-9-71ca.webp)
![(1R,5R)-3-{[(2-Methyl-2-propanyl)oxy]carbonyl}-3-azabicyclo[3.1.0]hexane-1-carboxylic acid structure (1R,5R)-3-{[(2-Methyl-2-propanyl)oxy]carbonyl}-3-azabicyclo[3.1.0]hexane-1-carboxylic acid structure](https://static.chemtradehub.com/structs/116/1165450-63-4-bfe1.webp)

![1-[4-(4-Methyl-1H-imidazol-1-yl)phenyl]ethanone structure 1-[4-(4-Methyl-1H-imidazol-1-yl)phenyl]ethanone structure](https://static.chemtradehub.com/structs/142/142161-53-3-7f55.webp)