The reaction of ‘GaI’ with a 1,3-diyne: synthesis, characterisation and reactivity of a novel C–C coupled ene–diyne–bis(gem-organodigallium(iii)) complex

Literature Information

Publication Date 2003-01-14
DOI 10.1039/B210868M
Impact Factor 6.222
Authors

Robert J. Baker, Cameron Jones


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Abstract

Treatment of ‘GaI’ with a 1,3-diyne, Me3SiCCCCSiMe3, leads to C–C coupling reactions and the isolation of the novel organogallium species, [Ga4I8{C8(SiMe3)4}], as two isomeric forms; their X-ray crystal structures show them to contain the first structurally authenticated gem-organodigallium fragments and to exhibit rare examples of Ga–alkyne π-interactions.

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