Direct Zn–diamine promoted reduction of CO and CN bonds by polymethylhydrosiloxane in methanol

Literature Information

Publication Date 2002-12-20
DOI 10.1039/B210144K
Impact Factor 6.222
Authors

Virginie Bette, André Mortreux, Christian W. Lehmann


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Abstract

Ketones and imines are chemoselectively reduced at room temperature in methanol to the corresponding alcohols and amines in high yields in a one-step procedure using polymethylhydrosiloxane (PMHS) and a simple zinc–diamine catalyst.

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