The (butadiene)metal complex/B(C6F5)3 pathway to homogeneous single component Ziegler–Natta catalyst systems
Literature Information
Publication Date
2003-04-25
DOI
10.1039/B208898N
Impact Factor
6.222
Authors
View Original
Abstract
The Lewis acid B(C6F5)3 adds to a variety of (butadiene)metal systems to yield zwitterionic complexes that are active homogeneous Ziegler–Natta type olefin polymerization catalysts. The new compounds have been useful in experimental studies gaining information about details of the carbon–carbon coupling reactions at these often fast and selective catalyst systems.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
(2R,2'R)-1,1'-Bis(2-pyridinylmethyl)-2,2'-bipyrrolidine tetrahydrochloride
CAS Number:
1228077-88-0
Molecular Formula:
C20H30Cl4N4
![5,7-Dihydroxy-3-(4-hydroxyphenyl)-6-[(1R,6R)-3-methyl-6-prop-1-en-2-ylcyclohex-2-en-1-yl]chromen-4-one structure](https://static.chemtradehub.com/structs/191/1914963-20-4-2b05.webp "5,7-Dihydroxy-3-(4-hydroxyphenyl)-6-[(1R,6R)-3-methyl-6-prop-1-en-2-ylcyclohex-2-en-1-yl]chromen-4-one structure")
5,7-Dihydroxy-3-(4-hydroxyphenyl)-6-[(1R,6R)-3-methyl-6-prop-1-en-2-ylcyclohex-2-en-1-yl]chromen-4-one
CAS Number:
1914963-20-4
Molecular Formula:
C25H24O5
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