EPR spectrum and formation properties of a cubic Rh+ centre in NaCl

Literature Information

Publication Date 2002-04-26
DOI 10.1039/B110906P
Impact Factor 3.676
Authors

H. Vrielinck, F. Callens, P. Matthys


View Original

Abstract

A cubic Rh+ centre in NaCl is studied with electron paramagnetic resonance (EPR) at Q-band (34 GHz). Its ΔMS = 1 EPR spectrum is shown to be broadened due to random distortions, lowering the cubic symmetry. At high microwave power, a sharp double quantum transition is observed, which exhibits a partially resolved hyperfine structure. From the formation conditions of this paramagnetic centre in solution and melt-grown NaCl crystals, its Rh2+ precursor centres are determined.

Related Literature

Selective decomposition of nucleic acids by laser irradiation on probe-tethered gold nanoparticles in solution

Yoshihiro Takeda, Tamotsu Kondow, Fumitaka Mafuné

2010-11-01 Paper

DOI: 10.1039/C0CP00770F

Excitation energy transfer in donor–bridge–acceptor systems

Bo Albinsson, Jerker Mårtensson

2010-06-16 Perspective

DOI: 10.1039/C003805A

Monodisperse Pt3Conanoparticles as electrocatalyst: the effects of particle size and pretreatment on electrocatalytic reduction of oxygen

Chao Wang, Guofeng Wang, Dennis van der Vliet, Kee-Chul Chang, Nenad M. Markovic, Vojislav R. Stamenkovic

2010-06-04 Paper

DOI: 10.1039/C000822B

Six conformers of neutral aspartic acid identified in the gas phase

M. Eugenia Sanz, Juan C. López, José L. Alonso

2010-03-05 Paper

DOI: 10.1039/B926520A

Photoelectron spectroscopy of homogeneous nucleic acid base dimer anions

Yeon Jae Ko, Haopeng Wang, Rui Cao, Dunja Radisic, Soren N. Eustis, Sarah T. Stokes, Svetlana Lyapustina, Shan Xi Tian, Kit H. Bowen

2010-02-11 Paper

DOI: 10.1039/B924950H

Direct ab initio MD study on the interaction of hydroperoxy radical (HOO) with water molecules

Hiroto Tachikawa, Shigeaki Abe

2010-02-24 Paper

DOI: 10.1039/B923310E

Self-organized distribution of periodicity and chaos in an electrochemical oscillator

Melke A. Nascimento, Hamilton Varela

2010-10-13 Paper

DOI: 10.1039/C0CP01038C

Contents

Front/Back Matter

DOI: 10.1039/C004143M

Coexistence of √3 × √3 and quasi-linear phases of sulfur adsorbed (Θ = 1/3) on a gold (111) substrate

Sandra Carolina Gómez-Carrillo

2010-10-29 Paper

DOI: 10.1039/C0CP00534G

You might also like

Compound Q&A

How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?

Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...

100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A

How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?

7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...

1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A

What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?

2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...

124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A

Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?

1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...

1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A

What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?

The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...

113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A

What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?

3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...

163271-80-53-(Triisopropylsilyl...
Compound Q&A

What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?

6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...

81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A

How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?

Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...

885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A

What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?

N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...

55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A

What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?

6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...

1036756-15-66-Bromo-8-fluoro-2-q...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.