Black body radiation induced hydrogen formation in hydrated vanadium cations V+(H2O)n

Literature Information

Publication Date 2002-05-01
DOI 10.1039/B110849B
Impact Factor 3.676
Authors

Brigitte S. Fox, Iulia Balteanu, O. Petru Balaj, Haichuan Liu, Martin K. Beyer, Vladimir E. Bondybey


View Original

Abstract

Hydrated vanadium cations V+(H2O)n, n = 5–30, are stored in the collision-free environment of an FT-ICR mass spectrometer and their reactions due to absorption of black body radiation are studied. Besides the loss of water ligands, the clusters show two different intracluster redox reactions, whose branching ratios are strongly size-dependent. Oxidation to the +II state results in V(OH)+(H2O)n ions, and a concurrent release of atomic hydrogen. Alternatively V(OH)2+(H2O)n clusters can form leaving vanadium in the +III state, common in aqueous solutions, and simultaneously molecular H2 evaporates from the cluster. This behavior reflects the properties of transition metals, and the ability of vanadium to form stable compounds in a variety of oxidation states, and differs from the previously studied intracluster reactions involving the hydrated monovalent main group metals Mg+ and Al+. These only react to their preferred oxidation states, MgOH+ and Al(OH)2+, respectively.

Related Literature

Radical polymers in optoelectronic and spintronic applications

Hyunki Yeo, Suman Debnath, Baiju P. Krishnan

2023-12-20 Perspective

DOI: 10.1039/D3LP00213F

Structural engineering of catalysts for ammonia electrosynthesis from nitrate: recent advances and challenges

Wenxi Qiu, Yuanting Liu, Minghao Xie, Zhaoyu Jin, Panpan Li, Guihua Yu

2023-09-26 Review Article

DOI: 10.1039/D3EY00184A

Enhanced H2 production at the atomic Ni–Ce interface following methanol steam reforming

Yaqi Hu, Zhong Liang, Yabin Zhang

2023-11-10 Paper

DOI: 10.1039/D3EY00225J

Sequential extraction of high-value added molecules from grape pomaces using supercritical fluids with water as a co-solvent

Karen Trchounian, Laurine Buon, Laurence Noret, Benoît Pinel, Jeremy Lagrue, Ali Assifaoui

2023-09-04 Paper

DOI: 10.1039/D3SU00183K

Reaction microenvironment control in membrane electrode assemblies for CO2 electrolysis

Dunfeng Gao, Juan-Jesús Velasco-Vélez, Guoxiong Wang

2023-09-13 Perspective

DOI: 10.1039/D3EY00155E

Inside front cover

2024-01-11 Cover

DOI: 10.1039/D4EY90002B

Boosting the catalytic performance of metal–zeolite catalysts in the hydrocracking of polyolefin wastes by optimizing the nanoscale proximity

Xinlei Han, Xinru Zhou, Tuo Ji, Feng Zeng, Weiping Deng, Zhenchen Tang, Rizhi Chen

2023-10-09 Paper

DOI: 10.1039/D3EY00180F

Modified Cu–Zn–Al mixed oxide dual function materials enable reactive carbon capture to methanol

Chae Jeong-Potter, Martha A. Arellano-Treviño, W. Wilson McNeary, Alexander J. Hill, Daniel A. Ruddy, Anh T. To

2023-11-08 Communication

DOI: 10.1039/D3EY00254C

Back cover

2023-11-27 Cover

DOI: 10.1039/D3VA90042H

You might also like

Compound Q&A

How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?

Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...

100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A

How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?

7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...

1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A

What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?

2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...

124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A

Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?

1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...

1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A

What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?

The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...

113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A

What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?

3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...

163271-80-53-(Triisopropylsilyl...
Compound Q&A

What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?

6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...

81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A

How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?

Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...

885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A

What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?

N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...

55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A

What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?

6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...

1036756-15-66-Bromo-8-fluoro-2-q...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.