The pressure dependence of self-diffusion and spin–lattice relaxation in cold and supercooled H2O and D2O

Literature Information

Publication Date 2002-03-25
DOI 10.1039/B110639M
Impact Factor 3.676
Authors

M. R. Arnold, H.-D. Lüdemann


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Abstract

Measurements of the self-diffusion coefficients D and the oxygen-17 and deuterium spin–lattice relaxation times T1 in light and heavy water have been extended into the supercooled region to a maximum pressure of 400 MPa and to a minimum temperature of 240 K and partly to even lower temperatures. With these measurements the maxima of the T1 isotherms could be established for the first time. For the deuterium and oxygen-17 T1 of heavy water as well as for the oxygen-17 T1 of light water the maxima occur around 250 MPa, their position being independent of temperature. Previously established maxima in the D-isotherms for both liquids are found at around 150 MPa. The heights of the maxima increase strongly with decreasing temperature. The increase in mobility with pressure is much more pronounced for the rotational mobility as given by T1 than for the translational mobility characterised by the self-diffusion coefficient. This anomaly, which appears to have been observed experimentally in cold water only, is discussed qualitatively.

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Inside front cover

Cover

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Contents list

Front/Back Matter

DOI: 10.1039/C3GC90031B

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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