Electrodeposition at polarisable liquid|liquid interfaces: The role of interfacial tension on nucleation kinetics
Literature Information
Christoffer Johans, Peter Liljeroth, Kyösti Kontturi
The influence of surfactants on nucleation at liquid|liquid interfaces was studied by cyclic voltammetry and chronoamperometry. The surface activity of a nanoparticle was considered within classical thermodynamics. These considerations indicated that while large particles preferentially reside in the interfacial region, small particles are not surface active. This results in a second critical radius in nucleation experiments. The experiments where the interfacial tension was changed by addition of a surfactant were in line with theoretical predictions.
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![9H-Fluoren-9-ylmethyl {15-[(2,5-dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}carbamate structure 9H-Fluoren-9-ylmethyl {15-[(2,5-dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}carbamate structure](https://static.chemtradehub.com/structs/131/1314378-14-7-4316.webp)