Active control of product selection in a chemical reaction: a view of the current scene

Literature Information

Publication Date 2002-04-11
DOI 10.1039/B109911F
Impact Factor 3.676
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Abstract

A brief overview is given of active control of product selection in a chemical reaction. Attention is then focussed on the use of coherent superpositions of states to control molecular dynamics. Both adiabatic and non-adiabatic population transfer generated by use of coherent superpositions of states are considered. After discussion of the optical control of the molecular dynamics of isolated molecules, a plausible model for the influence of solvent on the states of a solute molecule is introduced. Studies using this model imply that optical control of molecular dynamics in liquid solution should be possible.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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