A re-analysis of the vacuum ultraviolet absorption spectrum of I2, Br2, and ICl using ionization energies determined from their ZEKE-PFI photoelectron spectra

Literature Information

Publication Date 2002-03-21
DOI 10.1039/B109555M
Impact Factor 3.676
Authors

Trevor Ridley, David A. Beattie, Martin C. R. Cockett, Kenneth P. Lawley, Robert J. Donovan


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Abstract

The vacuum ultraviolet absorption spectra of I2, Br2 and ICl have been re-analysed using new data from the zero kinetic energy-pulsed field ionization (ZEKE-PFI) photoelectron spectra of all three molecules, and the (2 + 1) resonance enhanced multiphoton ionization (REMPI) spectrum of ICl. A common pattern of absorption intensities emerges in which all transitions to states which have appreciable singlet character are strong. Thus, in all three molecules, strong transitions are observed to four np and six nf Rydberg series based on the X[2Π3/2]g and X[2Π1/2]g states of the molecular ions, to two ns and six nd states in ICl and to two ns states based on the A[2Π3/2]u and A[2Π1/2]u states of the ion in Br2. The Ω values of some of the Rydberg series have been determined directly from the (2 + 1) REMPI spectrum of ICl.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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