A generic equation of state for the hard-sphere fluid incorporating the high density limit

Literature Information

Publication Date 2001-06-29
DOI 10.1039/B102972J
Impact Factor 3.676
Authors

Leonid V. Yelash, Thomas Kraska


View Original

Abstract

Based on an analysis of the virial coefficients of some hard-sphere fluid models a generic equation for the hard-sphere fluid is developed. This equation reproduces the correct high density limit. The generic equation provides the basis of a hierarchy of hard-sphere terms for different levels of simplification. As a result of this investigation a new hard-sphere term is developed by a simple linear regression of the virial coefficients in suitable coordinates. This term accurately represents the virial coefficients from B2 to B10 and gives the nearly correct pole packing fraction.

Related Literature

An enhanced capillary electrophoresis method for characterizing natural organic matter

Barbara A. Cottrell, Wei Ran Cheng, Buuan Lam, William J. Cooper, Andre J. Simpson

2012-12-18 Paper

DOI: 10.1039/C2AN36144B

An integrating strategy for serum metabolomics and microarray analysis to expand the understanding of diet-induced obesity

Wuping Liu, Jingjing Xu, Tao Dai, Guiping Shen, Jianghua Feng

2021-06-15 Paper

DOI: 10.1039/D1AY00821H

All-solid-state reference electrodes based on conducting polymers

Anna Kisiel, Honorata Marcisz, Agata Michalska, Krzysztof Maksymiuk

2005-10-27 Paper

DOI: 10.1039/B510868C

Back cover

Cover

DOI: 10.1039/C9AN90024A

Optimization of sensors based on encapsulated algae for pesticide detection in water

Víctor Oestreicher, Mercedes Perullini, Sara A. Bilmes, Matías Jobbágy, Sophie Dulhoste, Rémy Bayard, Claude Durrieu

2019-11-15 Paper

DOI: 10.1039/C9AY02145K

PEGylated NALC-functionalized gold nanoparticles for colorimetric discrimination of chiral tyrosine

Xin-Yue Chen, Wei Ha, Xiao-Jie Jin, Yan-Ping Shi

2020-08-20 Paper

DOI: 10.1039/D0AN01460E

Inside front cover

Cover

DOI: 10.1039/C9AY90155H

Simultaneous multiple enantioseparation with a one-pot imprinted microfluidic channel by microchip capillary electrochromatography

Ping Qu, Jianping Lei, Jin Sheng, Lei Zhang, Huangxian Ju

2010-11-29 Paper

DOI: 10.1039/C0AN00559B

Back cover

Cover

DOI: 10.1039/C3AN90087H

You might also like

Compound Q&A

How is Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) typically synthesized?

Ethyl 4-chlorothieno[2,3-b]pyridine-5-carboxylate (CAS: 59713-58-5) can be synth...

59713-58-5Ethyl 4-chlorothieno...
Compound Q&A

What regulatory guidelines apply to 5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2)?

5-Methyl-1H-indole-3-carbaldehyde (CAS: 52562-50-2) is subject to various regula...

52562-50-25-Methyl-1H-indole-3...
Compound Q&A

What are the physical and chemical properties of (1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid (CAS: 223418-73-3)?

(1,3-Dimethyl-2,4-dioxo-1,2,3,4-tetrahydro-5-pyrimidinyl)boronic acid is a white...

223418-73-3(1,3-Dimethyl-2,4-di...
Compound Q&A

How should waste containing Sulfocostunolide A (CAS: 1016983-51-9) be handled?

Waste containing Sulfocostunolide A (CAS: 1016983-51-9) should be handled with c...

1016983-51-9Sulfocostunolide A
Compound Q&A

What precautions should be taken when handling Murraxocin (CAS: 88478-44-8)?

When handling Murraxocin (CAS: 88478-44-8), ensure proper personal protective eq...

88478-44-8Murraxocin
Compound Q&A

What are the physical and chemical properties of Formvar (CAS: 63148-64-1)?

Formvar (CAS: 63148-64-1) is an alkyd resin characterized by a high molecular we...

63148-64-1Formvar(R)
Compound Q&A

Is (S)-4-benzyl-2-((benzyloxy)methyl)morpholine (CAS: 205242-66-6) safe?

(S)-4-benzyl-2-((benzyloxy)methyl)morpholine is generally safe when handled with...

205242-66-6(S)-4-benzyl-2-((ben...
Compound Q&A

What industries use Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3)?

Methyl 1-(5-bromo-2-pyrimidinyl)cyclopropanecarboxylate (CAS: 1447607-69-3) is p...

1447607-69-3Methyl 1-(5-bromo-2-...
Compound Q&A

Is 2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) safe?

2-Methyl-1-phenyl-1-propanamine hydrochloride (CAS: 24290-47-9) is generally con...

24290-47-92-Methyl-1-phenyl-1-...
Compound Q&A

How is 3-(4-Bromophenyl)-2-methylpropanoic acid (CAS: 66735-01-1) typically synthesized?

3-(4-Bromophenyl)-2-methylpropanoic acid is synthesized through a multi-step pro...

66735-01-13-(4-Bromophenyl)-2-...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.